There are 2 types of cleaning involved in soldering, they are mechanical and chemical.
Mechanical means abrasive type cleaning to remove surface oxidization.
Chemical involves cleaning after mechanical with some of degreaser (Isopropyl alcohol is the favoured but metho will work) then apply a flux to aid solder flow (it cleans the metal when heated).
Heat sinks are used to contain heat transfer and thus prevent damage as has been said previously locking pliers are very efficient.
Once the joint has cooled any remaining flux should be removed again with Iso or metho as in some cases if it is heated its corrosive effect can cause damage.
For soldering rail I use a mini blow torch and plumbers soldering fluid for electronics I have a couple of temp controlled irons.
From my RAAF training after you make a joint and have finished, tin the tip to prevent the iron corroding and turn off the iron if you are not using it for a couple of hours it will prolong tip life. At the end of the day always tin the tip.
Prior to soldering a joint wipe the tip on a damp (not wet) sponge to clean the tip
Basically cleanliness is next to godliness when it comes to efficient joints and as every old hippy knows good joints are everything,